一只完整的 5 cm² AEM 水電解槽。
該裝置包括耐腐蝕的 5 cm²陽極和陰極流場、帶有賤金屬催化劑的MEA、金屬氣體擴散層、o形密封圈和特氟龍襯墊。不包括加熱器或電纜。
該電解槽設計為在陽極和陰極上流動1M KOH,如Zengcai Liu等人所述。“膜對鹼性水電解槽的影響”
https://doi.org/10.1016/j.ijhydene.2017.10.050
這種鹼性水電解槽顯示出創紀錄的性能,因為它包含Sustainion陰離子交換膜
水電解槽用支撐膜的長期效果
使用說明
DM鹼水電解槽的初步設置
系統設定(推薦)
通常,系統設置使用蠕動泵測量1M KOH溶液,該溶液從具有兩個獨立氣體分離的公共溶液儲層均勻地分到陽極和陰極(圖1)。泵的總流量約為50 ml/分鐘。建議使用外徑為1/4英寸、內徑為1/8英寸的PTFE管。為了減少陽極和陰極之間的電流洩漏量(或分流電流),分成兩股流進入兩個電極室後,每側的管道長度應至少為8英寸(20 cm)。帶有兩個電極室氣體的出口液體流分別流向氣體分離器,氣體分離器允許液體落入單獨的部分,因此兩種產品氣體不會混合在一起。同時,氣體分離器也充當電流斷路器。
流體連接
流體入口和出口位於單元的中心(圖2)。將泵上的PTFE管(1/4“OD)連接到位於底部的壓縮配件;將另一個PTFE管(1/4”OD)從氣體分離裝置連接到頂部的壓縮配件;並用手指擰緊螺母。在電解槽的另一邊重複此步驟。
電源連接
將電線連接的螺紋孔定位在電池頂部(較小的通孔8-32螺紋)。然後用Phillips圓頭螺釘1連接環形端子。對陽極和陰極使用相同的步驟。
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圖 1.電解槽設置 | 圖 2. 25cm² 電解槽示意圖 |
電解槽測試和操作
以50 mL/min的速率從溶液儲罐和氣體分離器的底部連接處開始泵送1M KOH溶液,該溶液被分成兩個流,一個流到陽極室的入口,另一個流到陰極室。然後通過打開溫度控制器並將溫度設置為60°C(單獨出售的加熱器)開始加熱電池,並在通電前將溫度保持在60°C至少30分鐘。用電線/電纜(不包括)將電源上的陽極電線(紅色)和陰極電線(黑色)分別連接到正極和負極連接上。將電源電壓設置為2.2V,然後慢慢開始將電流增加至25 A(1A / cm²)。電解槽電流將在幾分鐘或幾小時內達到所需的25A,這取決於電池膜和電極的調節。也可以使用恒電位儀進行測試,但連接取決於測試方案。
A complete alkaline anion exchange membrane water electrolyzer. The unit includes corrosion resistant 25 cm2 anode and cathode flow fields, an MEA with base metal catalysts, metal gas diffusion layers, o-ring seals, and Teflon gasketing. No heaters or cabling included.
The electrolyzer is designed to be run with 1 M KOH flowing on the anode and cathode as described in Zengcai Liu et al. “The effect of membrane on an alkaline water electrolyzer” https://doi.org/10.1016/j.ijhydene.2017.10.050
Description
This alkaline water electrolyzer shows record performance because it contains Sustainion® anion exchange membranes
long term effect of Sustainion Membrane in water electrolyzer
Instructions for use
Initial set up for DM Alkaline Water Electrolyzer Cell
System set up (recommended)
Typically, the system setup uses a peristaltic pump to meter a 1M KOH solution that is split evenly to both the anode and cathode from a common solution reservoir with two separate gas disengagements (Figure 1). The total pump flowrate is about 50 mL/min. The suggested tubing used is a 1/4” OD, 1/8” ID PTFE tubing. The length of tubing after the split into the two flow streams into the two electrode compartments should be at least 8 inches (20 cm) on each side in order to reduce the amount of current leakage (or shunt current) between the anode and cathode. The exit liquid streams with gases from the two electrode compartments are separately routed to the gas disengager which allows the liquid to drop into the separate sections, so the two product gases are not mixed together. Meanwhile gas disengager also acts as a current break.
Fluid Connections
The fluid inlet and outlet ports are located in the center of the cell (Figure 2). Connect the PTFE tubing (1/4” OD) from the pump to the compression fitting located at the bottom; connect another PTFE tubing (1/4” OD) from the gas disengage to the compression fitting at the top; and tighten the nut with fingers. Repeat this for the other side of the cell.
Power Connections
Locate the threaded hole for wire connection on top of the cell (smaller through-hole 8-32 thread). Then connect the ring terminal with the Phillips round head screw. Use this same procedure for both anode and cathode.
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Figure 1. The electrolyzer setup | Figure 2. Diagram of the 25 cm2 cell |
Cell Testing and Operation
Begin pumping a 1M KOH solution from bottom connection of the solution reservoir and gas disengager at a rate of 50 mL/min which is split into two flow streams, one going to inlet of the anode chamber and the other to the cathode chamber. Then begin heating the cell by turning on the temperature controller and setting the temperature to 60°C (heaters sold separately) and holding the temperature at 60°C for at least 30 min before applying current. Connect the anode electrical lead (red) and cathode lead (black) to the positive and negative connections, respectively, on the power supply with electric wires/cables (not included). Set the power supply voltage at 2.2V and slowly begin increasing the current to a setting of 25 A (1A/cm2). The cell current will reach the desired 25A in a few min or hours depending on the cell membrane and electrode conditioning. Testing can also be done with potentiostat, but the connections depend on the testing protocol