產品介紹∣氧化還原液流電池 - 型號 1 (RFB1)
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氧化還原液流電池 - 型號 1 (RFB1)
Redox Flow Battery - Model 1 (RFB1)

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氧化還原液流電池 - 型號 1 (RFB1)

簡介

Redox Flow Battery - Model 1 (RFB1)

在圖片所示的標準配置中,此氧化還原液流電池測試池用於使用電化學技術(如循環伏安法 (CV)、電化學交流阻抗 (EIS) 和計時安培法/計時電位法)測試電極、膜和電解質。然而,由於採用模組化設計,此測量單元可以擴充或修改,以增加其功能。因此,它是可配置測量平台的基礎,可在此平台上整合一種或多種測量方法。

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在圖片所示的標準配置中,此氧化還原液流電池測試池用於使用電化學技術(如循環伏安法 (CV)、電化學交流阻抗 (EIS) 和計時安培法/計時電位法)測試電極、膜和電解質。然而,由於採用模組化設計,此測量單元可以擴充或修改,以增加其功能。因此,它是可配置測量平台的基礎,可在此平台上整合一種或多種測量方法。

舉例來說,可以更換為具有視窗的腔室,允許在電極表面進行拉曼光譜測量或傅立葉轉換紅外線光譜 (FTIR)。也可以將兩個腔體都換掉,以便在透射模式下進行 X 射線吸收光譜 (XAS) 或小角度 X 射線散射 (SAXS) 等光譜測量。這種功能擴展可以通過自定義來實現,因為每種情況下的規範要求通常不同。由於其獨特的設計,改變電極的活性表面面積或流場的幾何形狀,可透過輕易更換石墨流場來完成。

應用說明

氧化還原液流電池是一種可充電電池形式,能量儲存在液體電解質中,液體電解質中含有溶解的氧化還原活性物質(可進行還原和氧化的化合物)。這些液體儲存在外部儲存槽中,然後用泵抽過 RFB1,在 RFB1 中發生氧化還原反應,產生或儲存電力。外部水箱和泵不包含在產品中,但可根據要求添加。在放電過程中,陰極溶液會發生氧化反應,釋放出電子,而陽極溶液則會發生還原反應,接受電子。電子流經外部電路,產生電力。充電時,使用外部電源反轉過程。電解槽兩側之間的薄膜允許離子(但不允許氧化還原物)通過,以維持電荷平衡。

  

  

cell
active area: 25 cm², 4 cm² or 1 cm² (other on request)
channel cross-section area: 1 mm²

temperature sensor
sensor type: Pt100 x2 (100 W at 0 ºC)
construction: Wire-Wound, 10 mm tails
fundamental interval: 38.5 W (nominal)
self-heating: 0.02 to 0.3 ºC/mW
thermal response: <0.4 s
measuring current: 1 mA
diameter: 1.5 mm
length: 15 mm
tolerance class (IEC 60751): Class A
temperature range: -200 ºC to +650 ºC
body material: alumina

adhesive-backed pad heater
power source: electric
voltage: max 60 V
power: max 59 W
resistance: 61 W
material: polyimide
maximum temperature: 250 ºC
wire type: silicone braided wire
insulating resistance: >5 MW
size: 50 mm x 50 mm
thickness: <0.266 mm
adhesive: 3M
wire length: 60 mm

fittings
body material: Stainless Steel 316
connection 1 size: 1/4 in. tube OD (6.35 mm)
connection 1 type: Swagelok® Tube Fitting
connection 2 size: 7/16-20 in.
connection 2 type: male SAE/MS straight thread
reference: Swagelok® part #: SS-400-5-4ST

Intrastat data
HS Code: 90278080
Country of Origin: Sweden
NET weight: 2000 g

List of materials
anode flow field: synthetic graphite
cathode flow field: synthetic graphite
threaded end plate: Stainless Steel 316L
unthreaded end plate: Stainless Steel 316L
flow connection plate: PEEK
alignment pins: PEEK
current collectors: gold coated (nickel interlayer) copper (101)
fittings: Stainless Steel 316
bolts: zinc yellow-chromate plated steel grade 8
gaskets: skived PTFE and FKM
washers: Stainless Steel18/8
Belleville washers: Stainless Steel 302
temperature sensor body: Stainless Steel 316
adhesive-backed pad heater: polyimide with 3M adhesive

Setup includes
1 x anode with parallel flow field
1 x anode with parallel flow field and flow resistance compensation
1 x cathode with parallel flow field
1 x cathode with parallel flow field and flow resistance compensation
1 x threaded end plate 
1 x unthreaded end plate 
2 x flow connection chamber
2 x alignment pin
2 x current collector
4 x Swagelok® part #: SS-400-5-4ST fitting
8 x bolt
10 x FKM gasket
10 x skived PTFE gasket 
16 x washer
64 x Belleville washer
2 x Pt100 temperature sensor
2 x adhesive-backed pad heater

In the standard configuration shown in the images, this Redox Flow Battery test cell is used for testing electrodes, membranes, and electrolytes using electrochemical techniques such as Cyclic Voltammetry (CV), Electrochemical Impedance Spectroscopy (EIS) and Chronoamperometry/Chronopotentiometry. However, thanks to its modular design, this cell can be expanded or modified to increase its functionality. It is, therefore, the base of a configurable measurement platform on which it is possible to integrate one or several of many measurement methods. For example, it is possible to replace the chamber with one that has a window, allowing Raman spectroscopy measurements or Fourier transform infrared spectroscopy (FTIR) on the electrode surface. It is also possible to replace both chambers to enable spectroscopic measurements such as X-ray Absorption Spectroscopy (XAS) or Small-Angle X-ray Scattering (SAXS) in transmission mode. This kind of functionality extension is possible through customization, as the specification requirements are usually different in each case.
Thanks to its unique design, changing the active surface area of the electrode or the geometry of the flow field is accomplished through easy replacement of graphite flow fields.

Application note
A redox flow battery is a type of rechargeable battery where energy is stored in liquid electrolytes that contain dissolved redox-active species (compounds that can undergo reduction and oxidation). These liquids are stored in external tanks and pumped through the RFB1, where the redox reactions take place, generating or storing electricity. External tanks and pumps are not included with the product but can be added upon request. During the discharge, the anolyte undergoes oxidation, releasing electrons, while the catholyte undergoes reduction, accepting electrons. Electrons flow through an external circuit, producing electricity. During charge, the process is reversed using an external power source. A membrane between the two sides of the cell allows ions (but not the redox species) to pass, maintaining charge balance.

  

  

cell
active area: 25 cm², 4 cm² or 1 cm² (other on request)
channel cross-section area: 1 mm²

temperature sensor
sensor type: Pt100 x2 (100 W at 0 ºC)
construction: Wire-Wound, 10 mm tails
fundamental interval: 38.5 W (nominal)
self-heating: 0.02 to 0.3 ºC/mW
thermal response: <0.4 s
measuring current: 1 mA
diameter: 1.5 mm
length: 15 mm
tolerance class (IEC 60751): Class A
temperature range: -200 ºC to +650 ºC
body material: alumina

adhesive-backed pad heater
power source: electric
voltage: max 60 V
power: max 59 W
resistance: 61 W
material: polyimide
maximum temperature: 250 ºC
wire type: silicone braided wire
insulating resistance: >5 MW
size: 50 mm x 50 mm
thickness: <0.266 mm
adhesive: 3M
wire length: 60 mm

fittings
body material: Stainless Steel 316
connection 1 size: 1/4 in. tube OD (6.35 mm)
connection 1 type: Swagelok® Tube Fitting
connection 2 size: 7/16-20 in.
connection 2 type: male SAE/MS straight thread
reference: Swagelok® part #: SS-400-5-4ST

Intrastat data
HS Code: 90278080
Country of Origin: Sweden
NET weight: 2000 g

List of materials
anode flow field: synthetic graphite
cathode flow field: synthetic graphite
threaded end plate: Stainless Steel 316L
unthreaded end plate: Stainless Steel 316L
flow connection plate: PEEK
alignment pins: PEEK
current collectors: gold coated (nickel interlayer) copper (101)
fittings: Stainless Steel 316
bolts: zinc yellow-chromate plated steel grade 8
gaskets: skived PTFE and FKM
washers: Stainless Steel18/8
Belleville washers: Stainless Steel 302
temperature sensor body: Stainless Steel 316
adhesive-backed pad heater: polyimide with 3M adhesive

Setup includes
1 x anode with parallel flow field
1 x anode with parallel flow field and flow resistance compensation
1 x cathode with parallel flow field
1 x cathode with parallel flow field and flow resistance compensation
1 x threaded end plate 
1 x unthreaded end plate 
2 x flow connection chamber
2 x alignment pin
2 x current collector
4 x Swagelok® part #: SS-400-5-4ST fitting
8 x bolt
10 x FKM gasket
10 x skived PTFE gasket 
16 x washer
64 x Belleville washer
2 x Pt100 temperature sensor
2 x adhesive-backed pad heater