產品介紹∣薄膜電容去離子 ( MCDI ) 電解槽
Search

薄膜電容去離子 ( MCDI ) 電解槽
Membrane Capacitive Deionization configurable cell - MCDI configurable cell

【Redox.me】電化學周邊耗材 電化學流動系統

薄膜電容去離子 ( MCDI ) 電解槽

簡介

MCDI configurable cell

Membrane Capacitive Deionization (MCDI) 電解槽的設計目的,在於採用了多孔性碳電極與離子交換膜,以電吸附移除溶液中離子,並藉由離子滲透選擇性而減少同離子效應, 進而達到高能源效能的海水淡化( 脫鹽 ) 。

我要諮詢
Membrane Capacitive Deionization (MCDI) 電解槽的設計目的,在於採用了多孔性碳電極與離子交換膜,以電吸附移除溶液中離子,並藉由離子滲透選擇性而減少同離子效應, 進而達到高能源效能的海水淡化( 脫鹽 ) 。MCDI 電解槽包含兩個石墨電流收集器,可作為極化電極。但是,如果電極材料是研究的主題,則應該應用於另外的電流收集器,例如石墨紙或金屬氈 (不包含在產品中)。電解槽兩側可安裝不同的電極材料。如果這些電極的厚度超過 250 mm,則需要使用不同的墊片。在這種情況下,請聯絡我們尋求解決方案。
 
該單元的設計方式使得更換電極不需要去除膜或流場。擰下兩側的柱塞並更換電極就足夠了。在標準配置中,主通道和側邊通道中的液體流經由 PEEK 切割而成的流場。不過,也可以使用多孔材料(如毛氈或電池墊片)來取代這些材料,這樣就可以讓液體流動。如果,需要使用與規格表中所列尺寸不同的材料,我們可以提供不同厚度的密封件或客製化單元。該電解槽亦允許安裝一或兩片離子交換膜(不包括在設置中)。它們的厚度並不重要,也不需要調整壓緊它們的膜墊片的厚度。電解槽元件由樣品的惰性材料 (PEEK) 構成。它非常適合水性(FKM 墊圈和 O 形墊圈)和有機溶劑(FFKM 墊圈和 O 形墊圈)電解液的要求。該單元的結構是氣密的。

應用說明
MCDI電解槽可以配置為允許以下單元結構:
  1. 逐流式 CDI 包括:(i) 兩個塗有電容式(例如非法拉第)材料的多孔碳或金屬電流收集器,以及 (ii) 一個主流場,使給水能夠在電極之間輸送。在這種配置中,沒有安裝側流場和膜。
  2. 膜式CDI 包括:(i) 兩個塗有電容式(例如非法拉第)材料的多孔碳或金屬電流收集器,(ii) 兩個離子交換膜(陽離子交換膜和陰離子交換膜),將電極與主流場分開,以及 (iii) 一個主流場,使給水能夠在電極之間輸送。在此配置中,通常不會安裝側流場。然而,在某些情況下,安裝兩側流場是合理的。
  3. 倒置式 CDI 包含:(i) 兩個多孔碳或金屬電流收集器,其上塗有電容性 (如非法拉第) 材料,其中陽極處理為淨負面電荷,而陰極處理為淨正面電荷,以及 (ii) 一個主流場,使進水能在電極間傳輸。在此配置中,不安裝側流場和膜。
  4. 流動電極式 CDI 包含:(i) 兩個多孔碳或金屬電流收集器,其流動電極由電容式(例如非法拉第)碳懸浮液製成;(ii) 兩個離子交換膜(陽離子交換膜和陰離子交換膜),將電極與流動室分隔開;(iii) 一個主流場,可在電極之間輸送給水;(iv) 兩個側流場,用於液態電極。目前所提供產品形式均為此結構。
  5. 混合式 CDI 包含:(i) 用於陽離子吸附/解吸的法拉第(即電池)電極,(ii) 用於陰離子吸附/解吸的電容式(即非法拉第)電極,(iii) 放置在電容式電極旁邊的陰離子交換膜,以及 (iv) 使進水能在電極間傳輸的主流場。在此配置中,不安裝側流場和陽離子交換膜。
  6. 陽離子夾層海水淡化結構式包括:(i) 兩個塗有法拉第陽離子夾層材料的多孔碳或金屬電流收集器,(ii) 一個分隔電極的陰離子交換膜,以及 (iii) 一個可使給水在電極間輸送的主流場。在此配置中,不安裝一側流場和陽離子交換膜。
  7. 海水淡化結構式包括:(i) 兩個多孔碳或金屬電流收集器,表面塗有氧化還原 (例如非法拉第) 材料 (一個用於陽離子吸附/解吸,另一個用於陰離子吸附/解吸);(ii) 一個主流場,可使給水在電極之間輸送。在此配置中,不安裝側流場和膜。
      

      

tubing size: 4 mm OD
fitting type: push-in, M5 male
electrode size: 60 mm x 60 mm (36 cm2)
recommended total electrode thickness: 200-250 µm
membrane size: 70 mm x 85 mm
maximum operating pressure: 20 bar
maximum operating temperature 150 ºC

Intrastat data
HS Code: 90278080
Country of Origin: Sweden
NET weight: 1300 g

Product includes
2 x stand, anodized aluminum
2 x plunger holder, SS 316L
2 x PEEK plunger
2 x tantalum current collector
2 x graphite current collector
1 x threaded end plate, SS 316L
1 x unthreaded end plate, SS 316L
1 x PEEK outer cell body
1 x PEEK inner cell body
1 x set of fittings
2 x female banana connectors, 4 mm dia.
1 x PEEK main flow field, 0.5 mm thick
2 x PEEK side flow field, 0.5 mm thick
1 x set of gaskets (FKM or FFKM) including:

  • 1 x main flow gasket, 0.5 mm thick
  • 2 x membrane gasket, 0.25 mm thick
  • 2 x side flow gasket, 0.5 mm thick
  • 2 x electrode gasket, 0.25 mm thick
Membrane Capacitive Deionization (MCDI) configurable cell has been designed to conduct research on removal of charged ionic species from aqueous or organic solutions (i.e., Desalination/Demineralization) via electrostatic (i.e., non-Faradaic) or electrochemical (redox) interactions. The MCDI cell contains two graphite current collectors that can serve as polarization electrodes. However, if the electrode material is the subject of research, it should be applied to an additional current collector, such as graphite paper or metal felt (not included in the product). Different electrode materials can be installed on both sides of the cell. If the thickness of these electrodes exceeds 250 micrometers, different gaskets are required. In such a case, please contact us for a solution.
The cell is designed in such a way that replacing the electrodes does not require removing the membranes or flow fields. It is enough to unscrew the plungers on both sides and replace the electrodes. In the standard configuration, the liquid in the main channel and side channels flows through the flow field cut from PEEK. However, these can be replaced with a porous material such as felt or a battery spacer, which will allow fluid flow. If work with materials of dimensions different from those listed in the specification is required, we can supply seals of different thicknesses or customize the cell. The cell allows for the installation of one or two ion-exchange membranes (not included in the setup). Their thickness is not critical, and it is not necessary to adjust the thickness of the membrane gaskets pressing them. The cell elements are constructed with inert materials to the sample (PEEK). It well fits aqueous (FKM gaskets and O-rings) and organic solvent (FFKM gaskets and O-rings) electrolyte requirements. The construction of the cell is gas-tight.

Application note
MCDI cell can be configured to allow the following cell architectures:

  1. Flow-by CDI consisting of: (i) two porous carbon or metal based current collectors coated with capacitive (e. non-Faradaic) material, and (ii) a main flow field enabling the feed water to be transported between electrodes. In this configuration, side flow fields and membranes are not installed.  
  2. Membrane CDI consisting of: (i) two porous carbon or metal based current collectors coated with capacitive (e. non-Faradaic) material, (ii) two ion-exchange membranes (cation exchange membrane and anion exchange membrane) separating electrodes from the main flow field, and (iii) a main flow field enabling the feed water to be transported between electrodes. In this configuration, side flow fields are typically not installed. However, there are cases where installing both side flow fields is justified. All the graphics included in the product page refer to that configuration.
  3. Inverted CDI consisting of: (i) two porous carbon or metal based current collectors coated with capacitive (e. non-Faradaic) material where anode is treated for net negative surface charge and a cathode is treated for net positive surface charge, and (ii) a main flow field enabling the feed water to be transported between electrodes. In this configuration, side flow fields and membranes are not installed.  
  4. Flow-electrode CDI consisting of: (i) two porous carbon or metal based current collectors with flowing electrodes made of capacitive (e. non-Faradaic) carbon suspension, (ii) two ion-exchange membranes (cation exchange membrane and anion exchange membrane) separating electrodes from the flow chamber, (iii) a main flow field enabling the feed water to be transported between electrodes, and (iv) two side flow fields for liquid electrodes. All the graphics included in the product page refer to that configuration.
  5. Hybrid CDI consisting of: (i) a Faradaic (e. battery) electrode for cation adsorption/desorption, (ii) a capacitive (i.e. non-Faradaic) electrode for anion adsorption/desorption, (iii) an anion exchange membrane placed adjacent to the capacitive electrode, and (iv) a main flow field enabling the feed water to be transported between electrodes. In this configuration, side flow fields and a cation-exchange membrane are not installed.  
  6. Cation intercalation desalination consisting of: (i) two porous carbon or metal based current collectors coated with Faradaic cation intercalation materials, (ii) an anion exchange membrane separating electrodes, and (iii) a main flow field enabling the feed water to be transported between electrodes. In this configuration, one side flow field and cation-exchange membrane are not installed.  
  7. Desalination battery consisting of: (i) two porous carbon or metal based current collectors coated with redox (e. Faradaic) material (one for cation adsorption/desorption and the other for anion adsorption/desorption), and (ii) a main flow field enabling the feed water to be transported between electrodes. In this configuration, side flow fields and membranes are not installed.  



tubing size: 4 mm OD
fitting type: push-in, M5 male
electrode size: 60 mm x 60 mm (36 cm2)
recommended total electrode thickness: 200-250 µm
membrane size: 70 mm x 85 mm
maximum operating pressure: 20 bar
maximum operating temperature 150 ºC

Intrastat data
HS Code: 90278080
Country of Origin: Sweden
NET weight: 1300 g

Product includes
2 x stand, anodized aluminum
2 x plunger holder, SS 316L
2 x PEEK plunger
2 x tantalum current collector
2 x graphite current collector
1 x threaded end plate, SS 316L
1 x unthreaded end plate, SS 316L
1 x PEEK outer cell body
1 x PEEK inner cell body
1 x set of fittings
2 x female banana connectors, 4 mm dia.
1 x PEEK main flow field, 0.5 mm thick
2 x PEEK side flow field, 0.5 mm thick
1 x set of gaskets (FKM or FFKM) including:

  • 1 x main flow gasket, 0.5 mm thick
  • 2 x membrane gasket, 0.25 mm thick
  • 2 x side flow gasket, 0.5 mm thick
  • 2 x electrode gasket, 0.25 mm thick